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Photolysis of Fe(CO)₄²⁻ in Aqueous NaOH Glasses at 77 K. Formation of Solvated Electrons

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Kunkely, Horst ; Vogler, Arnd
Date of publication of this fulltext: 17 Mar 2010 06:22


The photolysis of [Fe(CO)4]2− in 10 M NaOH glass at 77 K leads to the formation of solvated electrons with θ = 0.03 at λirr = 254 nm. The solvated electrons, which are stable under these conditions, are identified by their characteristic absorption band at λmax = 588 nm.

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