Kunkely, Horst and Vogler, Arnd (1993) Photochemistry of cyclopentadienylthallium(I). Journal of Organometallic Chemistry 459 (1-2), pp. 21-23.
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Abstract
TlC5H5 displays absorption maxima at 228 and 280 nm which are assigned to metal-centred sp and ligand-to-metal charge transfer (LMCT) transitions, respectively. The complex shows an emission at λmax = 360 nm which originates from a low-energy sp excited state. The photolysis of TlC5H5 in methanol proceeds according to the equation TlC5H5 + CH3OH → TlOH + H2 + C6H6 (pentafulvene) with φ = 0.1 at ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 1993 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler | ||||
| Identification Number: |
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| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 13532 |
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