Photochemistry of cyclopentadienylthallium(I)

URN to cite this document:: urn:nbn:de:bvb:355-epub-135323
DOI to cite this document:: 10.5283/epub.13532

Kunkely, Horst ; Vogler, Arnd

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Date of publication of this fulltext: 17 Mar 2010 06:22

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Abstract

TlC5H5 displays absorption maxima at 228 and 280 nm which are assigned to metal-centred sp and ligand-to-metal charge transfer (LMCT) transitions, respectively. The complex shows an emission at λmax = 360 nm which originates from a low-energy sp excited state. The photolysis of TlC5H5 in methanol proceeds according to the equation TlC5H5 + CH3OH → TlOH + H2 + C6H6 (pentafulvene) with φ = 0.1 at ...