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Phase Transfer Photolysis of Metal Hexacarbonyls

URN to cite this document:
urn:nbn:de:bvb:355-epub-135376
DOI to cite this document:
10.5283/epub.13537
Kunkely, Horst ; Vogler, Arnd
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Date of publication of this fulltext: 17 Mar 2010 09:04


Abstract

The photochemical conversion of M(CO)6 (M
= Cr, Mo, W) to M(CO)5X- (X= halogen) across a hexam/
water interface leads to a separation of the reactant and product. This process may be of general lmportence
for synthetic applications. Under suitable conditions inner-
filter and secondary photolysis can be avoided.


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