Kunkely, Horst, Pawlowski, V. and Vogler, Arnd (1994) Photoredox behavior of a trinuclear Ru(III), Ru(II), Co(III) complex induced by metal-to-metal charge transfer excitations. Inorganica Chimica Acta 225 (1-2), pp. 327-330.
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Abstract
The trinuclear complex (NH3)5CoIII(μ-NC)CoIII(CN)4(μ-CN)RuII(CN)53− shows a long wavelength absorption near 370 nm which is assigned to a metal-to-metal charge transfer (MMCT) transition from Ru(II) to the central Co(III) ion. Light absorption by this bands leads to a redox decomposition: (NH3)5CoIII(CN)4(μ-CN)RuII(CN)53−→5NH3+ Co2++CoIII(CN)63−+ RuIII(CN)5H2O2−. It is suggested that the initial ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 1994 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler | ||||
| Identification Number: |
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| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 13566 |
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