Spectrophotometric studies of the photolysis of diazido-bis(phosphine)-metal(II) complexes

URN to cite this document:: urn:nbn:de:bvb:355-epub-135705
DOI to cite this document:: 10.5283/epub.13570

Hennig, H. ; Ritter, K. ; Knoll, H. ; Vogler, Arnd

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Date of publication of this fulltext: 17 Mar 2010 09:10

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Abstract

The photolysis of mixed ligand complexes of the type MLn(N3)2 (M=Ni, Pd, Pt; L = phosphane and diphosphane ligands, respectively; n = 1, 2) was monitored by electronic spectroscopy in absorption, emission and excitation. Initial quantum yields of these complexes were measured in CH2Cl2 and EtOH in dependence on the irradiation wavelength. Photochemically formed MOIn fragments of Pd and Pt are ...