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Photoredox Reaction of [Hg(cyclam)]²⁺[Co(CO)₄]⁻ Induced by Outer Sphere Charge Transfer Excitation

URN to cite this document:
urn:nbn:de:bvb:355-epub-135728
DOI to cite this document:
10.5283/epub.13572
Kunkely, Horst ; Vogler, Arnd
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Date of publication of this fulltext: 17 Mar 2010 09:06


Abstract

The ion pair [Hg(cyclam)]2+[Co(CO)4]- displays
a Co(-I) to Hg(II) metal-to-metal charge
transfer (MMCT) band at 288 nm. Upon MMCT
excitation the ion pair undergoes a photoconversion
to [HgC02(CO)8].


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