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Photoredox Reaction of [Hg(cyclam)]²⁺[Co(CO)₄]⁻ Induced by Outer Sphere Charge Transfer Excitation
Kunkely, Horst and Vogler, Arnd (1993) Photoredox Reaction of [Hg(cyclam)]²⁺[Co(CO)₄]⁻ Induced by Outer Sphere Charge Transfer Excitation. Zeitschrift für Naturforschung B 48, pp. 397-398.Date of publication of this fulltext: 17 Mar 2010 09:06
Article
DOI to cite this document: 10.5283/epub.13572
Abstract
The ion pair [Hg(cyclam)]2+[Co(CO)4]- displays
a Co(-I) to Hg(II) metal-to-metal charge
transfer (MMCT) band at 288 nm. Upon MMCT
excitation the ion pair undergoes a photoconversion
to [HgC02(CO)8].
Involved Institutions
Details
| Item type | Article |
| Journal or Publication Title | Zeitschrift für Naturforschung B |
| Volume: | 48 |
|---|---|
| Page Range: | pp. 397-398 |
| Date | 1993 |
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Keywords | Photoredox Reaction, Charge Transfer, Mercury(II), Cobalt(-I) |
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences |
| Status | Published |
| Refereed | Yes, this version has been refereed |
| Created at the University of Regensburg | Yes |
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-135728 |
| Item ID | 13572 |
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