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Photoluminescence of a triangular Hg₃⁴⁺ cluster

URN to cite this document:
urn:nbn:de:bvb:355-epub-135782
DOI to cite this document:
10.5283/epub.13578
Kunkely, Horst ; Vogler, Arnd
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Date of publication of this fulltext: 17 Mar 2010 09:13


Abstract

The cluster compound Hg3 (μ-dppm)3(SO4)2 (dppm = diphenylphosphinomethane) which contains the triangular Hg4+3 moiety shows an intense low-temperature ( 77 K ) photoluminescence at λmax = 658 nm. This emission is assumed to originate from a metal-centered ss excited state which undergoes a Jahn—Teller distortion.


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