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Electronic Spectra and Photochemistry of Trichlorostannyl Complexes of Rhodium(III) and Platinum(II)
Pawlowski, V., Kunkely, Horst and Vogler, Arnd (1994) Electronic Spectra and Photochemistry of Trichlorostannyl Complexes of Rhodium(III) and Platinum(II). Coordination Chemistry Reviews 132, pp. 23-28.Date of publication of this fulltext: 17 Mar 2010 09:36
Article
DOI to cite this document: 10.5283/epub.13594
Abstract
The absorption spectra of [Rh(SnCl3)4Cl2]3− and [Pt(SnCl3)5]3− are characterized by a similar band pattern. It is suggested that the absorption spectra are dominated by bands which are assigned to intraligand transitions. While solid (NBu4)3[Pt(SnCl3)5] shows a low-temperature emission the rhodium complex is not luminescent. Both complex anions are light sensitive in acetonitrile solution. They undergo an efficient photosubstitution of the trichlorostannyl ligand.
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| Item type | Article | ||||
| Journal or Publication Title | Coordination Chemistry Reviews | ||||
| Publisher: | Elsevier | ||||
|---|---|---|---|---|---|
| Volume: | 132 | ||||
| Page Range: | pp. 23-28 | ||||
| Date | 1994 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler | ||||
| Identification Number |
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| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-135948 | ||||
| Item ID | 13594 |
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