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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-135948
- DOI to cite this document:
- 10.5283/epub.13594
Alternative links to fulltext:DOI
Abstract
The absorption spectra of [Rh(SnCl3)4Cl2]3− and [Pt(SnCl3)5]3− are characterized by a similar band pattern. It is suggested that the absorption spectra are dominated by bands which are assigned to intraligand transitions. While solid (NBu4)3[Pt(SnCl3)5] shows a low-temperature emission the rhodium complex is not luminescent. Both complex anions are light sensitive in acetonitrile solution. They undergo an efficient photosubstitution of the trichlorostannyl ligand.
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