Kunkely, Horst and Vogler, Arnd (1994) Photochemistry of the Oxo-bridged Diiron(III) Core. Evolution of Oxygen induced by FeIII to FeII Charge-transfer Excitation of μ-Oxobis[(ethylenediaminetetraacetato)ferrate(III)]. Journal of the Chemical Society, Chemical Communications, pp. 2671-2672.
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Abstract
The reversible photolysis of aqueous [{FeIII(edta)}2O]4– leads to the evolution of oxygen and the formation of [FeII(edta)]2–; it is suggested that the photoreaction is induced by FeIII to FeIII charge-transfer excitation, which yields FeII and FeIVO in the primary photochemical step.
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 1994 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler | ||||
| Identification Number: |
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| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 13596 |
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