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Photochemistry of the Oxo-bridged Diiron(III) Core. Evolution of Oxygen induced by FeIII to FeII Charge-transfer Excitation of μ-Oxobis[(ethylenediaminetetraacetato)ferrate(III)]
Kunkely, Horst and Vogler, Arnd (1994) Photochemistry of the Oxo-bridged Diiron(III) Core. Evolution of Oxygen induced by FeIII to FeII Charge-transfer Excitation of μ-Oxobis[(ethylenediaminetetraacetato)ferrate(III)]. Journal of the Chemical Society, Chemical Communications, pp. 2671-2672.Date of publication of this fulltext: 17 Mar 2010 09:35
Article
DOI to cite this document: 10.5283/epub.13596
Abstract
The reversible photolysis of aqueous [{FeIII(edta)}2O]4– leads to the evolution of oxygen and the formation of [FeII(edta)]2–; it is suggested that the photoreaction is induced by FeIII to FeIII charge-transfer excitation, which yields FeII and FeIVO in the primary photochemical step.
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| Item type | Article | ||||
| Journal or Publication Title | Journal of the Chemical Society, Chemical Communications | ||||
| Page Range: | pp. 2671-2672 | ||||
|---|---|---|---|---|---|
| Date | 1994 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler | ||||
| Identification Number |
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| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-135968 | ||||
| Item ID | 13596 |
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