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Photochemistry of the Oxo-bridged Diiron(III) Core. Evolution of Oxygen induced by FeIII to FeII Charge-transfer Excitation of μ-Oxobis[(ethylenediaminetetraacetato)ferrate(III)]

URN to cite this document:
urn:nbn:de:bvb:355-epub-135968
DOI to cite this document:
10.5283/epub.13596
Kunkely, Horst ; Vogler, Arnd
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Date of publication of this fulltext: 17 Mar 2010 09:35


Abstract

The reversible photolysis of aqueous [{FeIII(edta)}2O]4– leads to the evolution of oxygen and the formation of [FeII(edta)]2–; it is suggested that the photoreaction is induced by FeIII to FeIII charge-transfer excitation, which yields FeII and FeIVO in the primary photochemical step.


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