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Proton tunnelling in the intramolecular hydrogen bond of 9-Hydroxyphenalenone

Weihrich, Richard, Limage, M.H., Parker, S.F. and Fillaux, F. (2004) Proton tunnelling in the intramolecular hydrogen bond of 9-Hydroxyphenalenone. Journal of Molecular Structure 700 (1-3), pp. 147-149.

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Inelastic neutron scattering spectra of the 9-hydroxyphenalenone and ring deuterated analogue reveal an intense band at 91 cm−1 with all characteristics anticipated for a tunnelling the transition of a (quasi)symmetric double minimum potential for proton transfer along the intramolecular hydrogen bond. This frequency is compared to those previously reported for similar systems.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Dr. Richard Weihrich
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Keywords:Hydrogen bond; 9-hydroxyphenalenone; Proton tunnelling; Inelastic neutron scattering
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:13922
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