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Charge transfer and chemical hardness along a substitution path in metastable Au-Sb alloys

Stückl, A. C. ; Rau, Franz ; Weihrich, Richard


In the present study the synthesis of metastable alloys of the noble metal Au and the semimetal Sb is realized by using high pressure techniques. The influence of Au on bulk Sb is shown experimentally by stepwise substitution. In addition to the effect of the most electronegative noble metal on Pauling's scale in the binary Au-Sb phases, some ternary compounds with In, Sn, As, and Te in addition ...


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