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Synthesis and application of chiral novel bis(isonitrile) ligands in catalysis

Naik, Anu (2011) Synthesis and application of chiral novel bis(isonitrile) ligands in catalysis. PhD, Universität Regensburg.

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Date of publication of this fulltext: 07 Apr 2011 08:10

Abstract (English)

This thesis describes the development and applications of new chiral bis(isonitrile) ligands in catalysis. These ligands are capable of forming very stable complexes with various transition metals such as Pd, Fe, Cu, Rh and Ir. Synthesis of the requisite bis(isonitrile) ligands was achieved in moderate yields via lithiation of 2-oxazolines and subsequent treatment with phenylphosphonic dichloride ...


Translation of the abstract (German)

Diese Arbeit beschreibt die Entwicklung und Anwendung neuer chiraler Bis(isonitril)-Liganden in der Katalyse. Diese Liganden sind in der Lage sehr stabile Komplexe mit verschiedenen Übergangsmetallen wie Pd, Fe, Cu, Rh und Ir zu bilden. Die Synthese der erforderlichen Bis(isonitril) liganden wurde in mäßigen Ausbeuten über Lithiierung von 2-Oxazolin und anschließender Behandlung mit ...


Export bibliographical data

Item type:Thesis of the University of Regensburg (PhD)
Date:7 April 2011
Referee:Prof. Dr. Oliver Reiser and Prof. Dr. Burkhard König and Prof. Dr. Manfred Scheer
Date of exam:30 March 2010
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Keywords:Bis(isonitrile) ligand, Wacker oxidation, transfer hydrogenation, imine hydrogenation, cyclopropanation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:14072
Owner only: item control page


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