The Unexpected Versatility of P4S3 as a Building Block in Polymeric Copper Halide Networks: 2,3-P, 1,2,3-P and all-P Coordination

DOI to cite this document:: 10.5283/epub.15135

Biegerl, Andreas ; Brunner, Eike ; Gröger, Christian ; Scheer, Manfred ; Wachter, Joachim ; Zabel, Manfred

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Date of publication of this fulltext: 07 Jun 2010 12:34

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Abstract

Layering solutions of P4S3 in CH2Cl2 with solutions of CuCl or CuI in CH3CN gives the coordination polymers (P4S3)3(CuCl)7 (1), (P4S3)2(CuCl)3 (2), (P4S3)(CuI) (3) and (P4S3)(CuI)3 (4), respectively, after slow diffusion. The yellow compounds were characterised by elemental analysis, 31P magic-angle spinning (MAS) NMR spectroscopy and single-crystal X-ray crystallography. The solid-state ...