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The Unexpected Versatility of P4S3 as a Building Block in Polymeric Copper Halide Networks: 2,3-P, 1,2,3-P and all-P Coordination

Biegerl, Andreas, Brunner, Eike, Gröger, Christian, Scheer, Manfred, Wachter, Joachim and Zabel, Manfred (2007) The Unexpected Versatility of P4S3 as a Building Block in Polymeric Copper Halide Networks: 2,3-P, 1,2,3-P and all-P Coordination. Chemistry - A European Journal 13 (33), pp. 9270-9276.

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Abstract

Layering solutions of P4S3 in CH2Cl2 with solutions of CuCl or CuI in CH3CN gives the coordination polymers (P4S3)3(CuCl)7 (1), (P4S3)2(CuCl)3 (2), (P4S3)(CuI) (3) and (P4S3)(CuI)3 (4), respectively, after slow diffusion. The yellow compounds were characterised by elemental analysis, 31P magic-angle spinning (MAS) NMR spectroscopy and single-crystal X-ray crystallography. The solid-state ...

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Item type:Article
Date:20 August 2007
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/chem.200700761DOI
Keywords:copper halides; NMR spectroscopy; phosphorus; polymers; sulfur
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:15135
Owner only: item control page

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