The Unexpected Versatility of P4S3 as a Building Block in Polymeric Copper Halide Networks: 2,3-P, 1,2,3-P and all-P Coordination

DOI to cite this document:: 10.5283/epub.15135

Biegerl, Andreas ; Brunner, Eike ; Gröger, Christian ; Scheer, Manfred

; Wachter, Joachim ; Zabel, Manfred

PDF
(468kB) - Repository staff only

Date of publication of this fulltext: 07 Jun 2010 12:34

Alternative links to fulltext:DOI

Details

Indexed in

Export bibliographical data

Abstract

Layering solutions of P4S3 in CH2Cl2 with solutions of CuCl or CuI in CH3CN gives the coordination polymers (P4S3)(3)(CuCl)(7) (1), (P4S3)(2)(CuCl)(3) (2), (P4S3)(CuI) (3) and (P4S3)(CuI)(3) (4), respectively, after slow diffusion. The yellow compounds were characterised by elemental analysis, P-31 magic-angle spinning (MAS) NMR spectroscopy and single-crystal X-ray crystallography. The ...