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The lowest excited state of brightly emitting Gold(I) triphosphine complexes

Czerwieniec, R. ; Hofbeck, T. ; Crespo, O. ; Laguna, A. ; Gimeno, M. C. ; Yersin, Hartmut.


The strongly luminescent neutral gold(I) triphosphine complexes [Au(dipnc)(PPh₃)] and [Au(dppnc)(PPH₃)] with dipnc = 7,8-bis(diisopropylphosphino)-nido-carborane ([(P/Pr₂)₂ B₉H10C₂)]⁻) and dppnc = 7,8-bis(diphenyl phosphino)-nido-carborane ([(PPh₂)₂ B₉H10C₂]⁻) are studied in a wide range of temperatures of 1.5 =< T =< 300K. Analysis of the emission decay dynamics provides detailed information ...


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