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Triplet state properties of a red emitting [Pt(s-thpy)(acac)] compound

Fischer, T. ; Czerwieniec, R. ; Hofbeck, T. ; Osminina, M. M. ; Yersin, Hartmut


A photophysical characterization based on optical high-resolution spectra and emission decay properties at low temperatures and at high magnetic fields is carried out for [Pt(s-thpy)(acac)] (s-thpy = 5,2-bis(2-thienyl)pyridinate and acac = acetylacetonate). The electronic 0-0 transition between the lowest triplet state and the ground state lies at 16150 cm⁻¹ (619 nm). The zero-field splitting ...


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