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Quinolizidine alkaloids from the curare adjuvant Clathrotropis glaucophylla

Sagen, Anne-Lise, Gertsch, Jurg, Becker, Rita, Heilmann, Jörg and Sticher, Otto (2002) Quinolizidine alkaloids from the curare adjuvant Clathrotropis glaucophylla. Phytochemistry 61 (8), pp. 975-978.

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Abstract

The bark of Clathrotropis glaucophylla (Fabaceae) is used as admixt. of curare arrow poison by the Yanomami Amerindians in Venezuela. A new quinolizidine alkaloid (QA), (-)-13alpha -hydroxy-15alpha -(1-hydroxyethyl)-anagyrine [(-)-clathrotropine] (I), was isolated from the alkaloid ext. of C. glaucophylla bark, together with eleven known QAs: (-)-anagyrine, (-)-thermopsine, (-)-baptifoline, ...

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Item type:Article
Date:2002
Additional Information (public):CAN 138:251471 11-1 Plant Biochemistry 485-35-8 ((-)-Cytisine); 486-86-2 ((-)-N-Methylcytisine); 486-88-4 ((-)-Lupanine); 486-89-5 ((-)-Anagyrine); 486-90-8 ((-)-Thermopsine); 529-78-2 ((-)-Rhombifoline); 732-50-3 ((-)-Baptifoline); 6835-75-2 ((-)-Epibaptifoline); 33023-11-9 ((-)-Tinctorine); 121312-83-2 ((+)-5,6-Dehydrolupanine); 278617-91-7 ((-)-6alpha -Hydroxylupanine) Role: NPO (Natural product occurrence), BIOL (Biological study), OCCU (Occurrence) (quinolizidine alkaloids from curare adjuvant Clathrotropis glaucophylla); 502686-87-5 ((-)-Clathrotropine) Role: NPO (Natural product occurrence), PRP (Properties), BIOL (Biological study), OCCU (Occurrence) (quinolizidine alkaloids from curare adjuvant Clathrotropis glaucophylla)
Institutions:Chemistry and Pharmacy > Institute of Pharmacy > Pharmaceutical Biology (Prof. Heilmann)
Identification Number:
ValueType
2002:895408Other
Keywords:New natural products ((-)-clathrotropine (quinolizidine alkaloid) Toxins (curare quinolizidine alkaloids from curare adjuvant Clathrotropis glaucophylla) Molecular structure (of (-)-clathrotropine) Bark Clathrotropis glaucophylla (quinolizidine alkaloids from curare adjuvant Clathrotropis glaucophylla) Alkaloids Role: NPO (Natural product occurrence), PRP (Properties), BIOL (Biological study), OCCU (Occurrence) (quinolizidine quinolizidine alkaloids from curare adjuvant Clathrotropis glaucophylla) Clathrotropis bark quinolizidine alkaloid curare
Dewey Decimal Classification:500 Science > 570 Life sciences
500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:No
Item ID:17206
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