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Magnetic field effects on the phosphorescence of Pt(4,6-dFppy)(acac) - Tunability of the vibrational satellite structure

Rausch, A. F. ; Yersin, Hartmut



Abstract

Effects of high magnetic fields on the properties of the lowest triplet state of the OLED emitter Pt(4,6-dFppy)(acac) are studied by site-selective high-resolution optical spectroscopy. Application of high fields strongly alters the pattern and magnitude of splitting of the triplet term, the oscillator strengths of the purely electronic 0-0 transitions between the T₁ substates and the singlet ...

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