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Photophysical properties and OLED applications of phosphorescent platinum(II) Schiff base complexes

Che, C.-M. ; Kwok, C.-C. ; Lai, S.-W. ; Zhu, N. ; Rausch, A. F. ; Finkenzeller, Walter J. ; Yersin, Hartmut


The syntheses, crystal structures, and detailed investigations of the photophysical properties of phosphorescent platinum(II) Schiff base complexes are presented. All of these complexes exhibit intense absorption bands with λ(max) in the range 417–546 nm, which are assigned to states of metal-to-ligand charge-transfer (¹MLCT) ¹[Pt(5d) ―› π*(Schiff base)] character mixed with ¹[lone ...


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