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Gold(I) complexes bearing P∩N-ligands: an unprecedented twelve-membered ring structure stabilized by aurophilic interactions

Monkowius, U., Zabel, Manfred, Fleck, M. and Yersin, Hartmut (2009) Gold(I) complexes bearing P∩N-ligands: an unprecedented twelve-membered ring structure stabilized by aurophilic interactions. Zeitschrift für Naturforschung B, a journal of chemical sciences 64b, pp. 1513-1524.

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Abstract

The P∩N-ligands Ph₂Pqn, 1, Ph₂Piqn, 2, Ph₂Ppym, 3, and the As∩N-ligands Ph₂Asqn, 4, Ph₂Asiqn, 5, (Ph = phenyl, qn = 8-quinoline, iqn = 1-isoquinoline, pym = 2-pyrimidine) have been synthesized, the ligands 2 and 5 for the first time. Their ligand properties were probed by the synthesis of gold(I) complexes. Reaction with (tht)AuCl (tht = tetrahydrothiophene) yielded the chlorogold complexes ...

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Item type:Article
Date:2009
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17378
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