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Probing the excited state properties of the highly phosphorescent Pt(dpyb)Cl compound by high-resolution spectroscopy

Rausch, A. F. ; Murphy, L. ; Williams, J. A. G. ; Yersin, Hartmut


Detailed photophysical studies of the emitting triplet state of the highly phosphorescent compound Pt(dpyb)Cl based on high-resolution optical spectroscopy at cryogenic temperatures are presented {dpyb = N^C²^N-coordinated 1,3-di(pyridylbenzene)}. The results reveal a total zero-field splitting of the emitting triplet state T₁ of 10 cm⁻¹ and relatively short individual decay times for the two ...


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