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μ-Bis (diphenylarsino)methane-κ² As: As'-bis[chlorodigold(I)]

Monkowius, U. ; Zabel, Manfred ; Yersin, Hartmut


The title structure, [Au₂Cl₂(C₂₅H₂₂As₂)], consists of discrete molecules disposed about a crystallographic twofold axis. The Au atom exhibits a nearly linear coordination by As and Cl atoms. Au…Au interactions [3.4285(4) Å] and a weak intermolecular C-H...Cl hydrogen bond are present.

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