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Photophysical properties of Re(pbt)(CO)₄ studied by high resolution spectroscopy

Czerwieniec, R. ; Finkenzeller, Walter J. ; Hofbeck, T. ; Starukhin, A. ; Wedel, A. ; Yersin, Hartmut



Abstract

Photophysical properties of Re(pbt)(CO)₄ are investigated at cryogenic temperatures and high magnetic fields. The highly resolved spectra show that the zero field splitting of the lowest triplet T₁ into three substates is smaller than 2 cm⁻¹. With this result, the T₁ state can be classified as only slightly MLCT-perturbed ³LC (³ππ*) state. Consistently, spin-lattice relaxation times are slow at T ...

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