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Bis[2-(diphenylphosphanyl)phenyl] ether-κ² P,P'] (1,1'-dibenzyl-1H,1'H-4,4'bi-1,2,3-triazole-κ²N³N³') copper(I) hexafluoridophosphate dichloromethane hemisolvate

Monkowius, U. ; Ritter, S. ; König, B. ; Yersin, Hartmut ; Zabel, Manfred



Abstract

In the crystal structure of the title compound, [Cu(C₁₈H₁₆N₆)(C₃₆H₂₈OP₂)]PF₆ 0.5 CH₂Cl₂ or [Cu(DPEPhos)(Bn-bta)]PF₆ 0.5 CH₂Cl₂ {DPEPhos = bis[(diphenylphosphanyl)phenyl] ether and Bn-bta = 1,1'-dibenzyl-1H,1'H-4,4'-bi-1,2,3triazole}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetrahedral environment. There are two crystallographically independent ...

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