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Bis[2-(diphenylphosphanyl)phenyl] ether-κ² P,P'] (1,1'-dibenzyl-1H,1'H-4,4'bi-1,2,3-triazole-κ²N³N³') copper(I) hexafluoridophosphate dichloromethane hemisolvate

Monkowius, U., Ritter, S., König, B., Yersin, Hartmut and Zabel, Manfred (2008) Bis[2-(diphenylphosphanyl)phenyl] ether-κ² P,P'] (1,1'-dibenzyl-1H,1'H-4,4'bi-1,2,3-triazole-κ²N³N³') copper(I) hexafluoridophosphate dichloromethane hemisolvate. Acta Crystallographica Section E E64, m195.

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Abstract

In the crystal structure of the title compound, [Cu(C₁₈H₁₆N₆)(C₃₆H₂₈OP₂)]PF₆ 0.5 CH₂Cl₂ or [Cu(DPEPhos)(Bn-bta)]PF₆ 0.5 CH₂Cl₂ {DPEPhos = bis[(diphenylphosphanyl)phenyl] ether and Bn-bta = 1,1'-dibenzyl-1H,1'H-4,4'-bi-1,2,3triazole}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetrahedral environment. There are two crystallographically independent ...

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Item type:Article
Date:2008
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1107/S1600536807066342DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:17404
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