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Proton spin–lattice relaxation rate in supercooled H₂O and H₂¹⁷O under high pressure

URN to cite this document:
urn:nbn:de:bvb:355-epub-174132
DOI to cite this document:
10.5283/epub.17413
Lang, Elmar ; Girlich, D ; Lüdemann, Hans-Dietrich ; Piculell, L. ; Müller, D.
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Date of publication of this fulltext: 22 Oct 2010 08:18


Abstract

The proton spin–lattice relaxation rate has been investigated as a function of pressure (p≤250 MPa), temperature (180 K≤T≤300 K), and oxygen‐17 enrichment (25.7 atom‐%, 50.7 atom‐%) in metastable water. Intramolecular proton–oxygen 17 dipolar interactions in light water in relation to deuterium electric quadrupole interactions in heavy water carry similar dynamic information and allow the ...

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