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Fink, W. ; Radkowitsch, H. ; Lang, Elmar

The p, T, c dependence of deuterium spin-lattice relaxation times in undercooled NaCl/D₂O and NaI/D₂O solutions

Fink, W., Radkowitsch, H. und Lang, Elmar (1988) The p, T, c dependence of deuterium spin-lattice relaxation times in undercooled NaCl/D₂O and NaI/D₂O solutions. Chemical physics = Chem. Phys. 124 (2), S. 239-249.

Veröffentlichungsdatum dieses Volltextes: 22 Okt 2010 08:03
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.17420


Zusammenfassung

Nuclear magnetic relaxation time measurements are well suited to monitor orientational and positional fluctuations of water molecules in solutions. Hence the dependence of deuteron spin-lattice relaxation rates on pressure (pless-than-or-equals, slant225 MPa), temperature (180less-than-or-equals, slantTless-than-or-equals, slant283 K) and composition (NaCl: cless-than-or-equals, slant5 m, NaI: ...

Nuclear magnetic relaxation time measurements are well suited to monitor orientational and positional fluctuations of water molecules in solutions. Hence the dependence of deuteron spin-lattice relaxation rates on pressure (pless-than-or-equals, slant225 MPa), temperature (180less-than-or-equals, slantTless-than-or-equals, slant283 K) and composition (NaCl: cless-than-or-equals, slant5 m, NaI: cless-than-or-equals, slant9.5 m) are reported in undercooled NaCl/D2O and NaI/D2O solutions over wide ranges of the external variables. The anomalous increase of molecular mobility upon compression, observed in neat undercooled water becomes less pronounced with increasing salt concentration until the pressure dependence reverts to normal behaviour at the edge of the glass forming composition range. This behaviour is qualitatively different from the recently studied systems LiCl- and MgCl2-D2O. In the presence of network breaking agents like hydrostatic pressure and/or ionic solutes molecular motions can be slowed down upon cooling sufficiently for the relaxation rates to exhibit a maximum and to become frequency dependent. Within a recently developed motional model a detailed account of orientational fluctuations of water molecules can be given and conclusions are drawn regarding the influence of structure and composition on molecular motions.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftChemical physics = Chem. Phys.
Verlag:Elsevier
Band:124
Nummer des Zeitschriftenheftes oder des Kapitels:2
Seitenbereich:S. 239-249
Datum1988
InstitutionenBiologie und Vorklinische Medizin > Institut für Biophysik und physikalische Biochemie > Prof. Dr. Elmar Lang
Identifikationsnummer
WertTyp
10.1016/0301-0104(88)87153-2DOI
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 570 Biowissenschaften, Biologie
StatusVeröffentlicht
BegutachtetUnbekannt / Keine Angabe
An der Universität Regensburg entstandenUnbekannt / Keine Angabe
URN der UB Regensburgurn:nbn:de:bvb:355-epub-174200
Dokumenten-ID17420

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