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Density dependence of the molecular dynamics of fluid CH₃ F and CF₃ H studied by NMR

URN to cite this document:
urn:nbn:de:bvb:355-epub-174223
Radkowitsch, H. ; Prielmeier, F. X. ; Lang, Elmar ; Lüdemann, H.-D.
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Date of publication of this fulltext: 22 Oct 2010 08:00


Abstract

The dynamic behaviour of compressed CH3F and CF3H has been studied between 150 and 400 K and to pressures of 200 MPa by measuring the spin-lattice relaxation times (T1) of the proton and fluor nuclei. Also the deuteron T1 of CD3F and CF3D were obtained in the whole p, T range. Both substances reveal a significant non-Arrhenian behaviour when the whole temperature range is studied. In addition the ...

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