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Synthesis, crystal structures, and electronic spectra of (1,8-naphthyridine)Re'(CO)₃Cl and [(1,8-naphthyridine)Cu'(DPEPhos)]PF₆

Monkowius, U. ; Svartsov, Y. N. ; Fischer, T. ; Zabel, Manfred ; Yersin, Hartmut



Abstract

Two 1,8-naphthyridine (nap) metal complexes (nap)Re'(CO)₃Cl (1) and [(nap)Cu'(DPEPhos)]PF₆ (2) were synthesized and characterized by NMR-, emission, and absorption spectroscopy, elemental analysis, mass spectrometry, and X-ray structural analysis. In both complexes, the nap ligand coordinates with both N atoms to the metal centre in a bidentate manner. 1 and 2 exhibit a broad phosphorescence in ...

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