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Crystal structures of fac-Ir(ppy)₃ and emission properties under ambient conditions and at high pressure

Breu, J. ; Stoessel, P. ; Schrader, S. ; Starukhin, A. ; Finkenzeller, Walter J. ; Yersin, Hartmut


Solution and refinement of the crystal structure of fac-Ir(ppy)₃ is severely hampered by systematic twinning and pseudo-symmetry. fac-Ir(ppy)₃ crystallizes in the centrosymmetric space group P3⁻ as has been deduced from single-crystal structure refinement and investigations of the second harmonic generation (SHG) of fac-Ir(ppy)₃ powder as compared to two standard materials. The topology of the ...


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