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Synthesis and photophysical properties of a series of biscyclometalated platinum(II) complexes on the basis of a tridentate 2,6-diphenylpyridine

Kulikova, M. V. ; Balashev, K. P. ; Yersin, Hartmut


Abstract

The complexes C,C-trans-[Pt(C^N^C)L]z [C^N^C is bisdeprotonated 2,6-diphenylpyridinate (dppy²⁻); L = CO, Me2SO (dmso), ethylenediamine (en), CN⁻, pyrazine (pz), P(C₆F₅)₃, 4,4'-bipyridine (4,4'-bpy)] were synthesized and characterized by ¹H NMR, electronic, and emission spectroscopy. Spectralluminescence properties of the chromophoric group (platinum-cyclometalating ligand) in the ...

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