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Emission of Ir(ppy)₃ - Temperature dependence, decay dynamics, and magnetic field properties

Finkenzeller, Walter J. and Yersin, Hartmut (2003) Emission of Ir(ppy)₃ - Temperature dependence, decay dynamics, and magnetic field properties. Chemical Physics Letters 377, pp. 299-305.

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Abstract

Emission spectra and decay times of fac-Ir(ppy)₃ dissolved in THF were registered for 1.2 K =< T =< 300 K and magnetic fields (at T = 1.5 K) up to B = 10 T. Three emissive triplet substates I, II, and III could be identified and classified as substates of a ³MLCT term of ³(Ir5d-ppyπ*) character. The energy separations and decay times are ΔE(II,I) = 13.5 cm⁻¹, ΔE(III,I) = 83 cm⁻¹ and τ(I) = 145 ...

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Item type:Article
Date:2003
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1016/S0009-2614(03)01142-4DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17458
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