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Energy transfer and harvesting in [Ru1-xOsx(bpy)₃](PF₆)₂ and {Λ-[Ru(bpy)₃] Δ-[Os(bpy)₃]}(PF₆)₄

Yersin, Hartmut and Kratzer, Cornelius (2002) Energy transfer and harvesting in [Ru1-xOsx(bpy)₃](PF₆)₂ and {Λ-[Ru(bpy)₃] Δ-[Os(bpy)₃]}(PF₆)₄. Coordination Chemistry Reviews 229 (1-2), pp. 75-93.

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Abstract

{Λ-[Ru(bpy)₃]Δ-[Os(bpy)₃]}(PF₆)₄ is the first representative of a new class of materials. The crystal structure is built up of homochiral layers of Λ-[Ru(bpy)₃]²⁺ that alternate with homochiral layers of Δ-[Os(bpy)₃]²⁺. In this new material, the excitation energy is transferred efficiently by radiationless processes to one single crystallographic site of Δ-[Os(bpy)₃]²⁺ (site A), where the ...

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Item type:Article
Date:2002
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17459
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