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Low-lying electronic states and photophysical properties of organometallic Pd(II) and Pt(II) compounds. Modern research trends presented in detailed case studies

Yersin, Hartmut ; Donges, D. Yersin, Hartmut , eds.


Abstract

Two homologous organometallic compounds, Pd(2-thpy)₂ and Pt(2-thpy)₂ (with 2-thpy⁻ = 2- (2-thienyl)-pyridinate, structure formulae in Fig. 1), are chosen for case studies of photophysical properties of the lowest excited states. The triplets of these two representative compounds are marked by differences of nearly two orders of magnitude in metal/MLCT (metal-to-ligand charge transfer) character. ...

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