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Low-lying electronic states and photophysical properties of organometallic Pd(II) and Pt(II) compounds. Modern research trends presented in detailed case studies

Yersin, Hartmut and Donges, D. (2001) Low-lying electronic states and photophysical properties of organometallic Pd(II) and Pt(II) compounds. Modern research trends presented in detailed case studies. In: Yersin, Hartmut, (ed.) Transition Metal and Rare Earth Compounds. Excited States, Trnsitions and Interactions. Volume II. Topics in Current Chemistry, 214. Springer, Berlin, Deutschland, pp. 81-186. ISBN 3-540-67976-6.

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Abstract

Two homologous organometallic compounds, Pd(2-thpy)₂ and Pt(2-thpy)₂ (with 2-thpy⁻ = 2- (2-thienyl)-pyridinate, structure formulae in Fig. 1), are chosen for case studies of photophysical properties of the lowest excited states. The triplets of these two representative compounds are marked by differences of nearly two orders of magnitude in metal/MLCT (metal-to-ligand charge transfer) character. ...

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Item type:Book section
Date:2001
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17462
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