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Triplets sublevels of metal organic complexes. Temperature dependence of spin-lattice relaxation

Strasser, J., Homeier, H. H. H. and Yersin, Hartmut (2000) Triplets sublevels of metal organic complexes. Temperature dependence of spin-lattice relaxation. Chemical Physics 255, pp. 301-316.

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Abstract

Triplets of transition metal complexes with organic chelate ligands can act as important pathways in photo-redox processes. Detailed information on these states is available from highly resolved optical spectra and time-resolved investigations. The lowest triplets are often zero-field split into sublevels by several cm⁻¹ (zero-field splitting, ZFS) due to spin-orbit interactions. Interestingly, ...

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Item type:Article
Date:2000
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17464
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