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Intra-ligand charge transfer in the Pd(II) oxinate complex Pd(qol)₂. Site-selective emission, excitation, and optical detected magnetic resonance

Yersin, Hartmut ; Donges, D. ; Nagle, J. K. ; Sitters, S. ; Glasbeek, M.


The first spectroscopic investigation of Pd(qol)₂ (qol⁻ = 8-quinolinolato-N, O = oxinate) dissolved in an n-octane matrix (Shpol'skii matrix) is reported. Application of several spectroscopic methods at liquid helium temperatures (typically, T = 1.2 K), such a site-selective and highly resolved luminescence and excitation spectroscopy, time-resolved emission spectroscopy, optically detected ...


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