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Organometallic Pt(II) and Ir(III) triplet emitter for OLED applications and the role of spin-orbit coupling - A study based on high-resolution optical spectroscopy

Rausch, A. F. ; Homeier, H. H. H. ; Yersin, Hartmut



Abstract

High-resolution optical spectroscopy of organometallic triplet emitters reveals detailed insights into the lowest triplet states and the corresponding electronic and vibronic transitions to the singlet ground state. As case studies, the blue-light emitting materials Pt(4,6-dFppy)(acac) and Ir(4,6-dFppy)₂(acac) are investigated and characterized in detail. The compounds' photophysical properties, ...

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