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Energy transfer and harvesting in [Ru1-xOsx(bpy)₃](PF₆)₂ and {Λ-[Ru(bpy)₃] Δ-[Os(bpy)₃]}(PF₆)₄

Yersin, Hartmut ; Kratzer, Cornelius


{Λ-[Ru(bpy)₃] Δ-[Os(bpy)₃]}(PF₆)₄ is the first representative of a new class of materials. The crystal structure is built up of homochiral layers of Λ-[Ru(bpy)₃]²⁺ that alternate with homochiral layers of Δ-[Os(bpy)₃]²⁺. In this new material, the excitation energy is transferred efficiently by radiationless processes to one single crystallographic site of Δ-[Os(bpy)₃]²⁺ (site A), where the ...


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