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Low-lying electronic states of [Rh(bpy)₃]³⁺, [Pt(bpy)₂]²⁺, and [Ru(bpy)₃]²⁺. A Comparative study based on highly frequency-resolved and time-resolved spectra

Yersin, Hartmut ; Humbs, W. ; Strasser, J.



Abstract

Optical emission and excitation spectra of [Rh(bpy-h₈)₃]³⁺, [Rh(bpy-h₈)₂(bpy-d₈)]³⁺, [Rh(bpy-d₈)₃]³⁺, [Pt(bpy-h₈)₂]²⁺, [Pt(bpy-h₈)(bpy-d₈)]²⁺, [Pt(bpy-d₈)₂]²⁺, [Ru(bpy-h₈)₃]²⁺, [Ru(bpy-h₈)₂(bpy-d₈)]²⁺, [Ru(bpy-d₈)₃]²⁺ are discussed. A series of trends - also including [Os(bpy)₃]²⁺ - is uncovered. These trends, which are connected with an increase in metal-d or MLCT character in the lowest ...

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