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Localization in excited states of molecules. Applications to [Ru(bpy)₃]²⁺

Yersin, Hartmut and Braun, D. (1991) Localization in excited states of molecules. Applications to [Ru(bpy)₃]²⁺. In: Belser, Peter, (ed.) Photochemistry and photophysics of coordination compounds: a collection of papers presented at the 9th international symposium, Fribourg, Switzerland, 14 - 19 July 1991. Coordination chemistry reviews, Special is. Elsevier, Amsterdam, pp. 39-46.

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Abstract

The properties of electron or exciton localization have been analyzed in solid state physics. Similar concepts can be applied to molecular systems, like [Ru(bpy)₃]²⁺. It is shown that an energy stabilization of the lower excited states through delocalization (order of 10³ cm⁻¹, mainly through the Ru4d-bpyπ* mixing) has to be exceeded by a stabilization energy, which results from a nuclear ...

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Item type:Book section
Date:1991
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17483
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