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Phonon mode coupling and Fano-type antiresonance in polyethylene

URN to cite this document:
Prettl, Wilhelm ; Frank, W. F. X.
Date of publication of this fulltext: 26 Oct 2010 12:22


The decrease of the absorption strength of 73 cm–1 line in polyethylene and the strong antiresonance occuring above 310 K at the high frequency wing of the line are explained by assuming a Fanto type coupling between the 73 cm–1 phonon and a continuum of infrared active vibrational modes. The parameters determining the line shape are deduced from experimental absorption curves and conceivable ...


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