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Ligand-centered 3ππ* emission and Raman activity of [Pt(bpy-h₈)n(bpy-d₈)2-n]²⁺ (n = 0, 1, 2)

Humbs, W. ; Yersin, Hartmut


Highly resolved emission and excitation spectra as well as emission decay data of [Pt(bpy-h₈)n(bpy-d₈)2 -n]²⁺ (n=0, 1, 2; bpy = 2,2'-bipyridine) are presented. These compounds are investigated as traps in neat [Pt(bpy)₂(CIO₄)₂ matrices. The traps, having their emitting states several cm⁻¹ below those of the majority of complexes, lead to spectral resolutions, which are by a factor of several ...


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