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Prettl, Wilhelm ; Rieder, K. H. ; Nitsche, R. N.

Raman scattering investigation and symmetry analysis of ferroelectric/ferroelastic Sb5O7I polytype 2MA

Prettl, Wilhelm, Rieder, K. H. und Nitsche, R. N. (1979) Raman scattering investigation and symmetry analysis of ferroelectric/ferroelastic Sb5O7I polytype 2MA. Zeitschrift für Physik B: Condensed Matter 32 (2), S. 215-224.

Veröffentlichungsdatum dieses Volltextes: 26 Okt 2010 12:28
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.17549


Zusammenfassung

The polytype 2MA (beta-Sb5O7I) has the simplest acentric structure of the antimony oxideiodide family. It undergoes an antiferrodistortive phase transition at 438K and is both ferroelectric and ferroelastic below that temperature. The complete polarized Raman spectra in the ferroic phase have been measured and compared with those of the ferroelastic, centric polytype 2MC (agr-Sb5O7I). Several ...

The polytype 2MA (beta-Sb5O7I) has the simplest acentric structure of the antimony oxideiodide family. It undergoes an antiferrodistortive phase transition at 438K and is both ferroelectric and ferroelastic below that temperature. The complete polarized Raman spectra in the ferroic phase have been measured and compared with those of the ferroelastic, centric polytype 2MC (agr-Sb5O7I). Several lines could be attributed to Sb—0 and Sb—I vibrations. A factor group analysis has been performed and compatibility relations have been established connecting phonon species in the low and high temperature phase. As a function of temperature the spectra revealed a strongly temperature dependent central line and several phonon lines whose intensities vanish aboveT c . Using these phonon line intensities the temperature variation of the order parameter could be determined. The experimental results indicate that the phase transition is of first order.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftZeitschrift für Physik B: Condensed Matter
Verlag:Springer
Band:32
Nummer des Zeitschriftenheftes oder des Kapitels:2
Seitenbereich:S. 215-224
Datum1979
InstitutionenPhysik > Institut für Experimentelle und Angewandte Physik > Entpflichtete oder im Ruhestand befindliche Professoren > Arbeitsgruppe Wilhelm Prettl
Identifikationsnummer
WertTyp
10.1007/BF01320117DOI
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 530 Physik
StatusVeröffentlicht
BegutachtetUnbekannt / Keine Angabe
An der Universität Regensburg entstandenUnbekannt / Keine Angabe
URN der UB Regensburgurn:nbn:de:bvb:355-epub-175497
Dokumenten-ID17549

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