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Raman scattering study and symmetry aspects of the phase transition in ferroelastic Sb5O7I
Prettl, Wilhelm und Rieder, K. H. (1976) Raman scattering study and symmetry aspects of the phase transition in ferroelastic Sb5O7I. Physical Review B (PRB) 14 (5), S. 2171-2179.Veröffentlichungsdatum dieses Volltextes: 26 Okt 2010 12:29
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.17551
Zusammenfassung
The low-frequency Raman spectra of ferroelastic Sb5O7I crystals have been measured for temperatures ranging from 295 K to well above the phase transition at Tc=481 K. A strongly damped soft mode which is present only in the ferroelastic phase and quasielastic scattering from a central line, whose intensity peaks around Tc, are observed. A symmetry analysis shows that the instability of the ...
The low-frequency Raman spectra of ferroelastic Sb5O7I crystals have been measured for temperatures ranging from 295 K to well above the phase transition at Tc=481 K. A strongly damped soft mode which is present only in the ferroelastic phase and quasielastic scattering from a central line, whose intensity peaks around Tc, are observed. A symmetry analysis shows that the instability of the hexagonal high-temperature phase may be explained by assuming a triply degenerate soft mode belonging to the star of the zone-boundary M point in the Brillouin zone. An expression for the free energy consistent with symmetry is constructed and the relation between the spontaneous elastic strain and the soft-mode amplitudes are determined. Applying this phenomenological theory it is shown that the intensities of several Raman lines, which decrease with rising temperature and vanish above Tc, are a measure of the temperature dependence of the order parameter. The experimental results indicate that the phase transition is weakly discontinuous.
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| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | Physical Review B (PRB) | ||||
| Verlag: | American Physical Society | ||||
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| Band: | 14 | ||||
| Nummer des Zeitschriftenheftes oder des Kapitels: | 5 | ||||
| Seitenbereich: | S. 2171-2179 | ||||
| Datum | 1 September 1976 | ||||
| Institutionen | Physik > Institut für Experimentelle und Angewandte Physik > Entpflichtete oder im Ruhestand befindliche Professoren > Arbeitsgruppe Wilhelm Prettl | ||||
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| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 530 Physik | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Ja, diese Version wurde begutachtet | ||||
| An der Universität Regensburg entstanden | Unbekannt / Keine Angabe | ||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-175517 | ||||
| Dokumenten-ID | 17551 |
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