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Determination of relaxation paths in the manifold of excited states of Pt(2-thpy)₂ and [Ru(bpy)₃]²⁺ by time-resolved excitation and emission

Schmidt, J. ; Strasser, J. ; Yersin, Hartmut


Abstract

Pt(2-thpy)₂ and [Ru(bpy)₃]²⁺, studied as representatives of transition metal complexes with zero-field splittings (zfs) of the lowest triplets of several cm⁻¹, exhibit a series of generally not-well known time dependencies of emission decay properties. These are strongly determined by relatively slow spin-lattice relaxation (slr) processes. Thus, one finds emission decays for [Ru(bpy)₃]²⁺ and ...

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