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Intra-ligand charge transfer in Pt(qol)₂. Characterization of electronic states by high-resolution Shol'skii spectroscopy

Donges, D. ; Nagle, J. K. ; Yersin, Hartmut


Pt(qol)₂ (qol⁻ = 8-quinolinolato-O,N) is investigated in the Shpol’skii matrices n-heptane, n-octane-h₁₈, n-octaned₁₈, n-nonane, and n-decane, respectively. For the first time, highly resolved triplet phosphorescence as well as triplet and singlet excitation spectra are obtained at T = 1.2 K by site-selective spectroscopy. This permits the detailed characterization of the low-lying singlet and ...


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