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Characterization of the lowest excited states of [Rh(bpy-h₈)n(bpy-d₈)3-n]³⁺ by highly resolved emission and excitation spectra

Humbs, W. and Yersin, Hartmut (1996) Characterization of the lowest excited states of [Rh(bpy-h₈)n(bpy-d₈)3-n]³⁺ by highly resolved emission and excitation spectra. Inorganic Chemistry 35, pp. 2220-2228.

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Abstract

Highly resolved emission, excitation, and resonantly line-narrowed spectra, as well as emission decay properties of [Rh(bpy-h₈)n(bpy-d₈)3-n]³⁺ (n = 0, 2, 3; bpy = 2,2'-bipyridine) doped into [Zn(bpy-h₈)₃](ClO₄)₂ are presented for the first time. [Rh(bpy-h₈)3]³⁺ and [Rh(bpy-d₈)₃]³⁺ exhibit one low-lying triplet T₁ at 22 757±1 and 22 818±1 cm⁻¹, respectively (blue shift 61 cm⁻¹), while ...

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Item type:Article
Date:1996
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1021/ic9510932DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17561
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