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Matrix deuteration effects and spin-lattice relaxation in the lowest triplet of the palladium(II)-complex Pd(2-thpy)₂

Becker, D., Yersin, Hartmut and v. Zelewsky, A. (1995) Matrix deuteration effects and spin-lattice relaxation in the lowest triplet of the palladium(II)-complex Pd(2-thpy)₂. Chemical Physics Letters 235, pp. 490-496.

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Abstract

Pd(2-thpy)₂ isolated in protonated or deuterated frozen n-octane (Shpol'skii matrices) exhibits highly resolved triplet emission and excitation spectra. One observes interesting differences for the two matrices: (i) The protonated matrix shows only one dominant guest site while the deuterated matrix exhibits two dominant sites. (ii) Low-energy satellites corresponding to lattice modes are ...

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Item type:Article
Date:1995
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:17584
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