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Extreme pressure-induced shifts of emission energies in M[Au(CN)₂] and M₂[Pt(CN)₄]•nH₂O - Compounds with low-dimensional metal-metal interactions

Yersin, Hartmut and Riedl, U. (1995) Extreme pressure-induced shifts of emission energies in M[Au(CN)₂] and M₂[Pt(CN)₄]•nH₂O - Compounds with low-dimensional metal-metal interactions. Inorganic Chemistry 34, pp. 1642-1645.

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Abstract

Emission properties of dicyanoaurates(I) and tetracyanoplatinates(II) are investigated under high hydrostatic pressure up to ca. 20 kbar and ca. 40 kbar, respectively, at T = 295 K. One observes pressure-induced red shifts of the emission energies, which are the largest values known for solid state compounds: Δν/Δp (cm⁻¹/kbar) = -120 (Cs₂Na[Au(CN)₂]₃); -150 (Cs[Au(CN)₂]); -200 (K[Au(CN)₂]); -300 ...

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Item type:Article
Date:1995
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17585
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