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Vibrational satellite structures and properties of electronic states of transition metal complexes

Yersin, Hartmut ; Huber, P. ; Wiedenhofer, H.



Abstract

Pd(2-thpy)₂, Pt(2-thpy))₂, [Ru(bpy-h₈)₃l²⁺, [Ru(bpy-h₈)₂(bpy-d₈)]²⁺, [Ru(bpy-d₈)s]²⁺, [Os(bpy-h₈)₃]²⁺, [Os(bpy-h₈)₂(bpy-d₈)]²⁺, and [Os(bpy-d₈)₃]²⁺ were isolated in crystalline matrices in order to obtain highly resolved emission spectra. A detailed analysis of the electronic origins and of the vibrational satellite structures reveals trends, which allow the various compounds to be ordered with ...

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