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Electron delocalization and localization in mixed-ligand [Ru(LL)n(LL')3-n]²⁺ complexes

Braun, D. ; Huber, P. ; Wudy, J. ; Schmidt, J. ; Yersin, Hartmut



Abstract

Highly resolved emission spectra of isolated [Ru(LL)n(LL')3-nJ²⁺ complexes doped into [Zn(bpy)₃](ClO₄)₂ with LL and LL' representing the ligands bpy-h₈, bpy-d₈, and bpz are presented. The information displayed in the electronic origins and the vibrational satellite structures combined with the emission decay behavior is used to provide a clear distinction between localized and delocalized MLCT ...

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