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Pressure and concentration dependent formation of oligomers of tetrakis(p-methylphenylisocyanide)rhodium(I)

Trümbach, D., Kritzenberger, J. and Yersin, Hartmut (1994) Pressure and concentration dependent formation of oligomers of tetrakis(p-methylphenylisocyanide)rhodium(I). Inorganica Chimica Acta 216 (1-2), pp. 245-247.

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The optical absorption of [Rh(tol)₄]PF₆ (tol p-methylphenylisocyanide) dissolved in acetonitrile has been measured as function of concentration (10⁻⁴ <= c(0) <= 1.5 X 10⁻² mol/l) and of applied pressure (0.1 <= p <= 400 MPa) at room temperature. Analysis of the spectra indicates the formation of oligomers [Rh(tol)₄]n“⁺, n = 2, 3 with increase of both the concentration and the pressure, ...


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Item type:Article
Date:February 1994
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17593
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