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Pressure and concentration dependent formation of oligomers of tetrakis(p-methylphenylisocyanide)rhodium(I)

Trümbach, D. ; Kritzenberger, J. ; Yersin, Hartmut


The optical absorption of [Rh(tol)₄]PF₆ (tol p-methylphenylisocyanide) dissolved in acetonitrile has been measured as function of concentration (10⁻⁴ <= c(0) <= 1.5 X 10⁻² mol/l) and of applied pressure (0.1 <= p <= 400 MPa) at room temperature. Analysis of the spectra indicates the formation of oligomers [Rh(tol)₄]n“⁺, n = 2, 3 with increase of both the concentration and the pressure, ...


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